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1 13 Cd-NMR studies of solutions of cadmium-loaded calmodulin (Cd 4 CaM) and the tetradecapeptide mastoparan in different ratios show that mastoparan binds to Cd 4 CaM with high affinity. The off-rate of proteinbound mastoparan is found to be 40 s -1 or less. The binding of one molecule of mastoparan to Cd 4 CaM is observed to affect all four metal-binding...
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