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Recent progress in understanding the structure and mechanism of nonheme iron dioxygenases is discussed; three classes of dioxygenases are reviewed — the intradiol cleaving catechol dioxygenases, the α-ketoglutarate dioxygenases, and lipoxygenase. In all three classes of enzymes, iron is essential for the catalysis of dioxygen fixation reactions, though the mechanisms by which these reactions are realized...
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