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Die Reaktivität der H‐Abstraktion durch Oxo‐Eisen(IV)‐Komplexe mit Quintett‐Grundzustand wird durch Austauschstabilisierung, die aus der steigenden Zahl an d‐d‐Austauschwechselwirkungen in der Nähe des Übergangszustands resultiert, stark erhöht (siehe Bild). Es wird postuliert, dass Nicht‐Häm‐Enzyme diesen fundamentalen Mechanismus zur Aktivierung von starken C‐H‐Bindungen nutzen.
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