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Calix[4]arene‐derived surfactants form monodisperse micelles with a well‐defined aggregation number (Nagg) of 4, 6, 8, 12, or 20, corresponding to the Platonic solids. This feature is in strong contrast to conventional micelles. In this study, a transition from a dodecamer (Nagg=12) to an icosamer (Nagg=20) was induced by a rapid increase in the NaCl concentration (CNaCl) using a stopped‐flow device...
CalixareneMicellen aus Calixaren‐Tensiden erfahren beim Anstieg der NaCl‐Konzentration einen Strukturübergang von Dodekameren zu Ikosameren, wie K. Sakurai et al. in ihrer Zuschrift auf S. 6838 ff. beschreiben. Der Übergang wurde durch zeitaufgelöste SAXS direkt beobachtet.
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