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Wasserstoff‐Aufnahme und ‐Freisetzung in Aren‐Cycloalkan‐Paaren ist eine vielversprechende Strategie zur Wasserstoffspeicherung, die aber durch die große Enthalpieänderung bei der Dehydrierung eingeschränkt wird. P. Chen, T. He, A. Wu et al. schildern in ihrer Zuschrift auf S. 3134, wie eine reversible Wasserstoffspeicherung unter moderaten Bedingungen mit einem natriierten Phenoxid‐Cyclohexanolat‐Paar...
Hydrogen uptake and release in arene–cycloalkane pairs provide an attractive opportunity for on‐board and off‐board hydrogen storage. However, the efficiency of arene–cycloalkane pairs currently is limited by unfavorable thermodynamics for hydrogen release. It is shown here that the thermodynamics can be optimized by replacement of H in the ‐OH group of cyclohexanol and phenol with alkali or alkaline...
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