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Luminescence behavior of Ru(bpy) 2+3 (bpy = 2,2 -bipyridine) and Ru(bpy)(bpds) 2-2 (bpds = 2,2 -bipyridine-4,4 -disulfonate dianion) in aqueous solution of cobalt(III)-complex-containing poly(methacrylic acid) (Co III PMA), which is affected by a unique pH-induced conformational transition, was investigated by means of fluorescence spectroscopy...
The conformational transition of poly(methacrylic acid-co-styrenesulfonic acid) (PMAS) in aqueous solution was investigated by the luminescence probe method using Ru(bpy) 2+3 and viscometry. PMAS-8 (8 mol% styrenesulfonic acid (SS) residue) and PMAS-16 (16 mol% SS residue) revealed a unique conformational transition with changing negative charge on a polymer chain that had at least...
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