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Herein we report on the preparation and structural characterization of six amphiphilic polymer conetworks (APCN) based on end‐linked amphiphilic “core‐first” star block copolymers, comprising methyl methacrylate and 2‐(dimethylamino)ethyl methacrylate as the monomer repeating units in the hydrophobic and hydrophilic blocks, respectively. The various APCNs differed either in the arm composition or...
A new general functionalization method (GFM) of synthesizing α‐functionalized polymers has been developed. α‐Vinyl‐functionalized polystyrene was obtained by anionic polymerization of styrene using 4‐pentenyllithium as an initiator. Chloromethyldimethylsilane‐functionalized polystyrene was successfully synthesized from vinyl‐functionalized polystyrene by hydrosilation using Karstedt's catalyst. Nucleophilic...
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