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Different surface sites of solid catalysts are usually quantified by dedicated chemisorption techniques from the adsorption capacity of probe molecules, assuming they specifically react with unique sites. In case of methanol synthesis catalysts, the Cu surface area is one of the crucial parameters in catalyst design and was for over 25 years commonly determined using diluted N2O. To disentangle the...
Einflussreiche Unterlage: Metallsubstrate nehmen Einfluss auf das Adsorptionsverhalten von ZnO‐Schichten, einem für die industrielle Herstellung von Methanol durch CO‐Oxidation wichtigen Katalysatormaterial. Wechselwirkungen mit dem Substrat führen zur Bildung einer neuen, planaren ZnO‐Schichtform, deren weniger hoch oxidierte Zn‐Atome CO stärker binden als die Zn‐Atome in der normalen Wurtzit‐Modifikation.
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