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FAD entrapped into the polyethyleneimine (PEI) matrix underwent 2e−/2H+ redox transformation, in contrast to the 1e−/1H+ reaction observed with non‐stabilized FAD‐modified electrodes. Under conditions of the 2e−/2H+ reaction, FAD/PEI‐modified electrodes catalytically oxidized NADH starting from −100 mV vs. Ag/AgCl. These electrodes may be used for construction of NAD‐dependent dehydrogenase electrodes...
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