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The superposition model is used to investigate the crystal field parameters, B_{kq} of Cr^{3+} in lithium potassium sulphate. The zero field splitting parameters D and E are then determined using microscopic spin Hamiltonian theory and compared with the experimental values obtained by electron paramagnetic resonance. Both zero field splitting parameters D and E evaluated theoretically are in good...
The superposition model has been used to investigate the substitution of Mn^{2+} in ammonium oxalate monohydrate. The zero field splitting parameters D and E calculated by the superposition model are compared with the experimental values D_{exp} and E_{exp}, respectively, for Mn^{2+} obtained by electron paramagnetic resonance. Both the zero field splitting parameters D and E calculated theoretically...
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