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Specific features of the crystal structure of bulk sphalerite-type Zn0.9Ni0.1S, Zn0.9V0.1Se, and Zn0.997Ni0.003Te crystals have been investigated in detail by thermal-neutron diffraction at room temperature. Fine effects (indicative of the existence of distortion microdomains, nucleation of long- and short-wavelength modulations, and tendencies toward local lowering of the symmetry based on the initial...
Neutron scattering patterns have been recorded for a bulk Zn0.9V0.1Se cubic crystal at room temperature; they are indicative of macroscopic deformation in the material and its significant inhomogeneity. Specific features of the previously found state, preceding the fcc ↔ hcp structural transformation of the sphalerite lattice upon strong destabilization induced by vanadium ions in the doped ZnSe matrix,...
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