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The chemoselective capabilities of porcine pancreatic lipase (PPL) in tetrahydrofuran andCandida rugosalipase (CRL) in diisopropyl ether have been investigated for selective acetylation and deacetylation of hydroxymethylated phenols and hydroxyaryl alkyl ketones and their peracetylated derivatives. Both PPL and CRL exhibited exclusive selectivity for the acetylation of alcoholic hydroxyl group over...
In recent years, enzymatic methodology has become a standard technique for the synthesis of a wide variety of enantiomerically pure precursors and target molecules. Reports on synthesis of nucleosides involving glycosyl transferring enzymes (covering literature up to October 1998) are summarized and discussed in this review.
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