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The fluorinated copolymer poly (MMA–co–FMA), composed of methyl methacrylate (MMA) and 2-perfluorooctylethyl methacrylate (FMA), was prepared by emulsion polymerization using a pre-emulsified monomer addition process. The results showed that the contact angle of water on its solvent-borne film increased dramatically and reached 118º when the FMA content in the copolymer was only 0.65 mol%, approaching...
SummaryIt is a challenge to fabricate fluorine-containing polymer surface with low-energy properties and superior long-lasting barrier properties as well as lower fluorine content. In this paper, poly(butyl methacrylate) end-capped with 2-perfluorooctylethyl methacrylate units (PBMA-ec-FMA) , having the so-called push-me/pull-you structures, have been synthesized by ATRP and their surface properties...
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