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Selective catalytic reduction of NO with acetylene (C 2 H 2 -SCR) over mordenite-based catalysts (HMOR, 0.5% Mo/HMOR and NaMOR) was investigated by in situ Fourier transform infrared spectroscopy. A possible mechanism was proposed to explain catalytic performance of the mordenite-based catalysts in the C 2 H 2 -SCR: Nitrosonium ions (NO + ) and bidentate nitrate...
Intermediate species formed on ZSM-5 zeolites during the selective catalytic reduction of NO by acetylene (C 2 H 2 -SCR) were investigated by transmittance FTIR and temperature-programmed desorption, to elucidate the different catalytic performance of the proton and sodium forms of ZSM-5. Bidentate nitrates formed exclusively on HZSM-5 were very active toward the reductant, whereas...
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