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Powering lithium‐ion batteries (LIBs) by light‐irradiation will bring a paradigm shift in energy‐storage technologies. Herein, a photoaccelerated rechargeable LIB employing SnO2/TiO2 heterojunction nanoarrays as a multifunctional anode is developed. The electron–hole pairs generated by the LixTiO2 (x ≥ 0) under light irradiation synergistically enhance the lithiation kinetics and electrochemical reversibility...
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