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Cu-based chalcogenides have received increasing attention as promising thermoelectric materials due to their high efficiency, tunable transport properties, high elemental abundance and low toxicity. In this review, we summarize the recent research progress on this large family compounds covering diamond-like chalcogenides and liquid-like Cu2X (X=S, Se, Te) binary compounds as well as their multinary...
We present how the applied Ar background pressure correlates to the cation and anion composition of Cu(I) chalcogenide thin films grown by pulsed laser deposition (PLD). The as-grown films produced at ∼10 −2 mbar p Ar show a more pronounced deficiency in lighter composition, as compared with using quasi-vacuum or ∼10 −1 mbar. The thermoelectric performance...
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