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Tough and transparent poly(methyl methacrylate) (PMMA) nanocomposites with the impact strength and breaking elongation 1.6 and 9.6 times higher than that of pure PMMA, separately, are obtained through in situ thermal polymerization of methylmethacrylate (MMA) gels with dumbbell-like organogelators (G1-alkyl). G1-alkyl is designed and synthesized with long alkyl chains at the periphery, which can self-assemble...
A two-component gelator (B1⋯C12⋯B1) based on interaction between dendritic branch (Branch1 (COOH)) and diaminododecane is designed and synthesized, and its self-assembly behavior in methyl methacrylate (MMA) is firstly investigated. It is interesting to find that the gel formation depends on the concentration and sonication during cooling of the B1⋯C12⋯B1/MMA solution. Sonication plays as a switch...
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