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A new conductive polyaniline derivative containing disulfide bonds, poly[bis(2-aminophenyloxy)disulfide] (PAPOD), has been proposed as a high energy-storage material. PAPOD has been synthesized using a moderate oxidant ferric chloride and characterized by elemental analysis, X-ray photoelectron spectroscopy (XPS), FT-IR, FT-Raman, and UV–vis spectroscopy. The cyclic voltammograms of this polymer show...
Electrical resistance measurements and FT-IR spectroscopy of polyaniline were studied in situ under ultra-high pressures generated by a diamond anvil cell (DAC). The electrical resistance of polyaniline decreased as the pressure increased, exhibiting polaron conductor characteristics. Minimum electrical resistance was observed at 3.6 GPa, about three orders of magnitude smaller than that at 1.0 GPa...
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