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Mixed matrix membranes (MMMs) based on metal–organic framework (MOF) have great promising application in separation of gas mixtures. However, achieving a good interfacial compatibility between polymer and MOF is not straightforward. In this work, focusing on one of the most challenging olefin/paraffin separations: propylene/propane (C3H6/C3H8), we demonstrate that modification of the MOF filler via...
The ZIF‐8@Agmim core‐shell hybrid material was synthesized via a favorable post‐modification method of ion exchange (PMIE). This infrequent ZIF‐8@Agmim core‐shell structure maintains a well‐integrated pore size that is almost the same as ZIF‐8. The similar equilibrium isotherms with ZIF‐8 and better kinetic separation toward propylene/propane than ZIF‐8 render ZIF‐8@Agmim to be an interesting candidate...