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The local structure of Mn‐doped Li2B4O7(001) was investigated using extended X‐ray absorption fine structure (EXAFS) at the Mn K edge and electron paramagnetic resonance (EPR). The location of the Mn dopant in a lithium tetraborate crystal is consistent with occupation of a site with strong oxygen coordination. The MnO bond lengths are similar to those observed with Mn doping of the icosahedral based...
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