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The dimerisation of 1-butene using (cod)Ni(hfacac) 1 as catalyst has been investigated in different chloroaluminate ionic liquids. Systems prepared by buffering an acidic ionic liquid with weak organic bases proved to be very suitable solvents for the reaction. The reaction takes place in biphasic reaction mode with facile catalyst separation and catalyst recycling. The high intrinsic dimer linearity...
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