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Sm filled CoSb 3 without charge compensation was synthesized at ambient pressure for the first time through a melt-annealing method. The synthetic Sm y Co 4 Sb 12 samples possess an Im3¯ symmetry of skutterudite structure. The lattice parameter expanded mildly after Sm inclusion into CoSb 3 lattice. A larger atomic displacement parameter (ADP) was revealed for...
Gadolinium filled CoSb 3 , which is inaccessible at ambient pressure with the traditional solid state reaction, was successfully synthesized by using a high pressure synthesis method within several hours. The synthetic Gd y Co 4 Sb 12 samples possess Im3¯ symmetry of skutterudite structure. The thermoelectric properties investigation revealed the enhancement of the...
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