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Planar chiral η 3 -allyldicarbonylnitrosyliron complexes were prepared by the reaction of optically active allyl tosylate and allyl bromide with tetrabutylammonium tricarbonyl nitrosylferrate. The optical purity and planar chirality of the complexes thus obtained depended on reaction solvents and leaving groups of the allylic substrates. Stereoselectivity of the complex forming reaction was...
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