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Abstract. A combination of sensitive calorimetry and neutron diffraction data is presented demonstrating the formation of solid monolayers for linear alcohols (c5 to c19) adsorbed from their liquids to a graphite surface. The results reveal a significant oddeven variation in the monolayer melting points, much bigger than the bulk alcohols, that appears to be structural in origin.
Molecular relaxation curves of five different polystyrene samples, four monodisperse of weight-average molecular weight ranging from 210 000 to 2 340 000, and one polydisperse, have been studied using birefringence and polarization modulation infrared linear dichroism, during and after a step-strain uniaxial deformation at temperatures between Tg and Tg+60°C. Relaxation measurements can be fitted...
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