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While WCl 6 -Ph 4 Sn is a poor catalyst for the polymerization of 1-phenyl-1-butyne (PB) at room temperature, it effectively polymerizes PB in the presence of C 60 , giving high molecular weight polymers in high yields. The polymers are soluble in common solvents such as THF and chloroform, and spectroscopic analysis reveals that C 60 has copolymerized with...
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