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A palladium chloride catalyzed Hiyama cross-coupling reaction between aryl halides and phenyltrimethoxysilane in toluene has been developed. High yields of products, as well as the obviation of ligand are important features of this method. The scope of the reaction is broad, and a wide variety of functional groups are tolerant.
A highly efficient ligand-free Suzuki cross-coupling reaction between aryl halides and aryl boronic acids using palladium chloride as catalyst in toluene has been developed. High yields of products, mild reaction conditions as well as the obviation of ligand are important features of this method. The palladium can be reused for four times.
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