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The selective hydroformylation of 1-hexene to branched aldehydes was investigated using rhodium complex of tri-1-naphthylphosphine PNp 3 and tri-1-naphthylphosphite P(ONp) 3 . The PNp 3 and P(ONp) 3 ligands having more steric nature than PPh 3 enhanced the formation of branched aldehydes at 110°C and 4.0MPa syngas pressure. The branched aldehyde selectivity...
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