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This review provides an overview of our explorations into oligosaccharide and glycoconjugate construction for the creation and evaluation of glycopeptide-based vaccines. The basis for these investigations is the known tendency of both cancer cells and viruses to express selective carbohydrate motifs in the form of glycoproteins or glycolipids. Utilization of these carbohydrates in a glycopeptide-based...
Chapter 8 consists of two vignettes, each providing personal accounts of the development of ring‐closing metathesis (RCM) approaches to the synthesis of natural products. In Vignette 1, Vanderwal describes how the structure of echinopines A and B inspired the discovery of an allylsilane RCM/electrophilic desilylation methodology for constructing carbocyclic rings with exocyclic alkenes. The implementation...
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