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We developed a protocol for the palladium‐catalyzed aminocarbonylation of aryl halides using less‐toxic formamide acetals as bench‐stable aminocarbonyl sources under neutral conditions. Various aryl (including heteroaryl) halides reacted with N,N‐dialkylformamide acetals in the presence of a catalytic amount of tris(dibenzylideneacetone)dipalladium(0)‐chloroform adduct and xantphos to give the corresponding...
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