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Methane and ethane are the most abundant and the least reactive members of the hydrocarbon family, and their selective conversion to useful chemical products is of great scientific, as well as practical, interest. This review highlights some of the recent advances in the area of low temperature, catalytic, activation and functionalization of methane and ethane. Particular emphasis has been placed...
At 600 °C, NOx catalyzes the partial oxidation of both methane and ethane by dioxygen to form formaldehyde. The yield of oxygenates from methane is over 11. The yield increases to over 16 when 0.7% of ethane is added to the gas mixture. The yield of oxygenates from ethane is over 24. A catalytic cycle involving NO2 as the C–H activating species is proposed.
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