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Multimetallic nitride species, especially those containing biologically related iron or molybdenum, are fundamentally important to understand the nitrogen reduction process catalysed by FeMo‐nitrogenase. However, until now, there remains no report about the construction of structurally well‐defined FeMo heteronuclear nitrido complex and its reactivity toward ammonia formation. Herein, a novel thiolate‐bridged...
Multimetallic nitride species, especially those containing biologically related iron or molybdenum, are fundamentally important to understand the nitrogen reduction process catalysed by FeMo‐nitrogenase. However, until now, there remains no report about the construction of structurally well‐defined FeMo heteronuclear nitrido complex and its reactivity toward ammonia formation. Herein, a novel thiolate‐bridged...
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