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The bdt-bridged diiron-amide complex [Cp∗Fe(μ-η2:η2-bdt)(μ-NH2)FeCp∗][BF4]2 (1[BF4]2, Cp∗=η5-C5Me5; bdt=benzene-1,2-dithiolate) and its reduction products [Cp∗Fe(μ-η2:η2-bdt)(μ-NH2)FeCp∗][BF4] (2[BF4]) and [Cp∗Fe(μ-η2:η1-bdt)(μ-NH2)FeCp∗] (3) have been synthesized. DFT calculations suggest that the sequential reduction of 1[BF4]2 to 2[BF4] and further to 3 is a bimetal and single-metal based process,...
The single-electron reduction of the thiolate-bridged diiron diazene complex [Cp*Fe(μ-SEt)2(μ-η1:η1-HNNH)FeCp*]+ (Cp*=η5-C5Me4H, 1+) to [Cp*Fe(μ-SEt)2(μ-η1:η1-HNNH)FeCp*] (2) has been computationally found to be a metal-based reduction process. Such a reduction event decreased the acidity of NH bond and increased the basicity of N atoms of the diazene moiety. The results derived from broken-symmetry...
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