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Maßgeschneiderte Adsorbentien …︁…︁ wurden entwickelt, die auf Metall‐organischen Gerüsten (MOFs) mit passend großen Porenöffnungen basieren. In der Zuschrift auf S. 14561 ff. konstruieren M. Eddaoudi et al. ein Seltenerdmetall‐fcu‐MOF mit dreieckigen Öffnungen, das verzweigte Paraffine mit unerreichter Selektivität von normalen Paraffinen trennt. Die optimale Öffnungsgröße lieferte der ditope Ligand...
Using isoreticular chemistry allows the design and construction of a new rare‐earth metal (RE) fcu‐MOF with a suitable aperture size for practical steric adsorptive separations. The judicious choice of a relatively short organic building block, namely fumarate, to bridge the 12‐connected RE hexanuclear clusters has afforded the contraction of the well‐defined RE‐fcu‐MOF triangular window aperture,...
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