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The title complex, [NiL](ClO 4 ) 2 was synthesized by the reaction of nickel(II) perchlorate and the new macrocycle ligand, 1,4,7,10-tetrakis(2-pyridylmethyl)-1,4,7,10-tetraazacyclododecane (L) in ethanol solution. The crystal and molecular structure of this complex has been determined by single-crystal X-ray diffraction. The complex consists of [NiL] 2+ cation and two...
The neodymium nitrate complex with 1,4-bis(phenylsulfinyl)butane(bphsb)[Ln(bphsb) 2 (NO 3 ) 3 ] n has been synthesized and characterized. The X-ray crystal structure determination of the complex indicates that bphsb and neodymium(III) ion form a polymeric chain involving 18-membered macrocycles, each macrocycle comprising two neodymium(III) ions. The adjacent metal...
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