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Auf dem Weg zur Katalyse: Zwei Äquivalente des Kupfer(II)‐amids [(Cl2NN)]Cu‐NHAd nehmen über eine Sequenz aus H‐Abstraktion und Radikaleinfang an stöchiometrischen C‐H‐Aminierungen teil (siehe Schema). Diese aktive Spezies entsteht vermutlich über ein Kupfer(II)‐tert‐butoxid‐Zwischenprodukt und sorgt für eine beispiellose katalytische Aktivierung von sp3‐C‐H‐Bindungen mit nichtaktivierten Alkylaminen...
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