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As alkyl-arenes are important feedstock chemicals, synthetic methods more atom economical than traditional Friedel-Crafts and bond-coupling reactions are needed. Pt II complexes have been experimentally demonstrated to facilitate olefin hydroarylation. A TpPt II catalyst model (Tp=hydrido-tris(pyrazolyl)borate) was selected for computational studies. Nickel's low cost prompted its...
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