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The reaction of the deprotonated form of the Schiff base ligand; (E)-2-methoxy-6-((phenylimino) methyl)phenol (L) with nickel chloride hydrate results in the formation of the 1-dimentional coordination polymer; Na[Ni(L)2(OMe)(MeOH)]n (1). The structure was determined via single crystal X-ray diffraction measurements. A careful analysis of the complex shows that the polymer exists as a helical structure,...
A novel hexanuclear complex [{(CuL) 2 Cu} 2 (μ-dca) 2 ](ClO 4 ) 2 ·2L′(1) (where H 2 L=(OH)C 6 H 4 C(CH 3 )N(CH 2 ) 3 NC(CH 3 )C 6 H 4 (OH) or N,N′-bis(2-hydroxyacetophenone) propylenediimine and dca=N(CN) 2− and L′=2-hydroxyacetophenone) has been synthesized and characterized...
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