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The unimolecular dissociation of ionized valeramide (n-C 4 H 9 CONH 2 ) is examined by mass spectrometric techniques. Photoionization (PI) experiments yield an ionization energy of 9.40+/-0.03eV. Besides the formation of the molecular ion, dissociation is observed close to the onset of PI. In addition to the PI experiments, the unimolecular dissociations of metastable valeramide...
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