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Methanol‐selektive Vapochromie …… wird in einem Nickel(II)‐Chinonoid‐Komplex realisiert, der bei der Aufnahme und Abgabe von Methanoldampf eine reversible Strukturumwandlung einschließlich einer Änderung der Koordinationsgeometrie zwischen einer quadratisch‐planaren und oktaedrischen Struktur eingeht. Wie M. Kato und Mitarbeiter in ihrer Zuschrift auf S. 2385 zeigen, wird der Prozess von einem bemerkenswerten...
A highly methanol‐selective vapochromic response has been realized in a NiII‐quinonoid complex, [Ni(HLMe)2] (H2LMe=4‐methylamino‐6‐methyliminio‐3‐oxocyclohexa‐1,4‐dien‐1‐olate) which exhibits a reversible structural transformation including a coordination geometrical change between the square‐planar and octahedral structure by the selective uptake of methanol vapor. This was accompanied by a remarkable...
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