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In 1992, Korkin and Schleyer studied in silico the structure of Si3H5- and concluded that the lowest-energy isomer of this anion has a non-planar C s structure. More recently, Xiao et al. claimed that a cyclic form is the global minimum structure. However, they did not compare the computed energy with any other structural options. In this manuscript we reexamine the Si3H5- structure by using...
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