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Based on a strategy of incorporating the SCN− group into the organically templated halocadmate, the reactions of CdCl2, SCN−, and bisimidazole molecules in a strong acidic environment at 4°C were carried out, creating two new organically templated 2-D layered thiocyanato-chlorocadmates [H2(L1)][Cd2Cl5(SCN)] (L1=bis(1H-imidazole-1-yl)methane) 1 and [H2L2]2[Cd5Cl12(SCN)2] (L2=1,3-bis(2-ethylimidazol-1-yl)propane)...
Based on an aim of introducing the SCN− or SO42− group into the organically templated chlorocadmates, a series of room-temperature reactions at pH 2 were performed, creating four new Cd(II) hybrids as [L1]4[Cd4Cl6(SCN)10(H2O)2] (L1=1,1′-dibenzyl-4,4′-bipyridium) 1, [H4L2][CdCl4(SCN)2] (L2=1,4-bis(4-pyridylmethyl)piperazine) 2, [HL3]3[CdCl3]SO4 (L3=2-amino-6-chloropyridine) 3, and [HL4]3[CdCl3]SO4...
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