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Three-component reactions involving Ni(II) ions and dicarboxylate and bipyridyl ligands under hydrothermal conditions produce two novel metal–organic coordination polymers formulated empirically as [Ni(PDA)(BPE)] (1) and [Ni 2 (PDA) 2 (BPP)(H 2 O)]·2.5H 2 O (2), where PDA=1,4-phenylenediacetate, BPE=1,2-bis(4-pyridyl)ethane, and BPP=1,3-bis(4-pyridyl)propane. Both compounds...
Hydrothermal reactions of Ln(NO 3 ) 3 (Ln=La, Eu) with 1,4-phenylenedipropionic acid (H 2 PDP) generate 3D coordination polymers with the empirical formula [Ln 2 (PDP) 3 (H 2 O) 2 ]. The isostructural compounds crystallize in triclinic space group P1¯. Each Ln(III) ion is nine-coordinate through ligation to one water molecule and eight carboxylate...
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