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Iridium complexes bearing chelating cyclometalates are popular choices as dopant emitters in the fabrication of organic light‐emitting diodes (OLEDs). In this contribution, we report a series of blue‐emitting, bis‐tridentate IrIII complexes bearing chelates with two fused five‐six‐membered metallacycles, which are in sharp contrast to the traditional designs of tridentate chelates that form the alternative,...
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