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Oxygen-ionic and electronic transport in dense (SrFe) 1−x (SrAl 2 ) x O z composites, consisting of strontium-deficient Sr(Fe,Al)O 3-δ and SrAl 2 O 4 phases, is determined by the properties of perovskite-like solid solution. Increasing the content of SrAl 2 O 4 , with a total conductivity as low as 5×10 −7 −10 −5 ...
The electrocatalytic activity of composite anodes, comprising metallic platinum and nanocrystalline Pt-modified Ce0.45Zr0.45La0.10O2-δ and Ce0.9Sm0.1O2-δ , was evaluated for the oxidation of dry methane in a solid oxide fuel cell (SOFC) – type reactor with yttria-stabilized zirconia solid electrolyte. At 923–1073 K, the total combustion is dominant, whilst above 1100 K the composite anodes exhibit...
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