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Titanium in the form of bulk and powder was processed by severe plastic deformation using high-pressure torsion (HPT) at cryogenic and room temperatures to investigate the influence of grain size on allotropic phase transformations. Almost a complete α (hexagonal close-packed, hcp) to ω (hexagonal) phase transformation occurred under a pressure of 6GPa at room temperature until the grain size reached...
A computational method having quantitatively predictive performance of L 2,3 ELNES/XANES of 3d transition metal (TM) compounds without any empirical parameter is given. Calculations are made on three TM monoxides with rock salt structures, MnO, FeO and CoO using model clusters composed of a TM ion with six coordinating oxide ions. Multi-electron wavefuctions are expressed by a linear combination...
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