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The superposition of intermolecular interactions and extrinsic forces can be used to control the properties of self‐assembled materials. On page 369 Samuel I. Stupp and co‐workers investigate the role of electric fields during the interfacial self‐assembly of a hierar‐chically ordered membrane from oppositely charged molecules and demonstrate profound changes in the growth rate and orientation, as...
Self‐assembly in the presence of external forces is an adaptive, directed organization of molecular components under nonequilibrium conditions. While forces may be generated as a result of spontaneous interactions among components of a system, intervention with external forces can significantly alter the final outcome of self‐assembly. Superimposing these intrinsic and extrinsic forces provides greater...
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