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Myoglobins (Mbs) reconstituted with rotatable octamethylheme and non-rotatable etioheme were prepared and their electrochemical behavior was studied. The redox potential of octamethylheme reconstituted Mb (OMe-Mb), of which heme rotates around iron-histidine (F8 His) bond, shifted negatively by ca. 30 mV compared with non-rotatable etioheme reconstituted Mb (Etio-Mb). On the other hand, the redox...
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