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Gel spun polyacrylonitrile/carbon nanotube (PAN/CNT) composite fibers have been produced, and the stress-induced G′ Raman band shifts in the CNTs have been monitored to observe stress transfer during fiber strain. Improvements in CNT quality, CNT dispersion, and post-processing fiber drawing are shown to increase the stress transfer from the matrix to the CNT. Radial breathing mode (RBM) intensity...
In this review, we show that the structure and behavior of single-walled nanotubes (SWNTs) are essentially polymeric; in fact, many have referred to SWNTs as “the ultimate polymer”. The classification of SWNTS as polymers is explored by comparing the structure, properties, phase behavior, rheology, processing, and applications of SWNTs with those of rigid-rod polymers. Special attention is given to...
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