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Einblicke auf atomarer Ebene beleuchten die Wechselwirkung zwischen Metall und Promotor in Rhodium‐basierten Katalysatoren für die Umwandlung von Synthesegas zu Ethanol. Wie X. Huang, M. G. Willinger, A. Trunschke und Mitarbeiter in ihrer Zuschrift auf S. 8801 berichten, führt diese Wechselwirkung im besten Katalysator (Rh auf Siliciumdioxid mit Mn und Fe als Promotoren) zur Bildung einer aktiven...
The direct conversion of syngas to ethanol, typically using promoted Rh catalysts, is a cornerstone reaction in CO2 utilization and hydrogen storage technologies. A rational catalyst development requires a detailed structural understanding of the activated catalyst and the role of promoters in driving chemoselectivity. Herein, we report a comprehensive atomic‐scale study of metal–promoter interactions...
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