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Carbocations such as cyclic carbenium ions are important intermediates in the zeolite‐catalyzed methanol‐to‐olefins (MTO) reaction. The MTO reaction propagates through a complex hydrocarbon pool process. Understanding the carbocation‐involved hydrocarbon pool reaction on a molecular level still remains challenging. Here we show that electron‐deficient cyclopentenyl cations stabilized in ZSM‐5 zeolite...
Zyklische Carbokationen sind wichtige Zwischenprodukte in der Methanol‐zu‐Olefin‐Reaktion (MTO) über Zeolithen. Im Forschungsartikel auf S. 27051 berichten Jun Xu und Mitarbeiter, dass die bei der MTO‐Reaktion gebildeten Carbokationen kleine Kohlenwasserstoffmoleküle über nicht‐kovalente Wechselwirkungen einfangen können. Multiple nicht‐kovalente Wechselwirkungen wurden durch Festkörper‐NMR‐Spektroskopie...
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